The Role of SnO2 Processing on Ionic Distribution in Double-Cation-Double Halide Perovskites

Holland Hysmith, So Yeon Park, Jonghee Yang, Anton Ievlev, Yongtao Liu, Kai Zhu, Bobby Sumpter, Joseph Berry, Mahshid Ahmadi, Olga Ovchinnikova

Research output: Contribution to journalArticlepeer-review

2 Scopus Citations

Abstract

Moving toward a future of efficient, accessible, and less carbon-reliant energy devices has been at the forefront of energy research innovations for the past 30 years. Metal-halide perovskite (MHP) thin films have gained significant attention due to their flexibility of device applications and tunable capabilities for improving power conversion efficiency. Serving as a gateway to optimize device performance, consideration must be given to chemical synthesis processing techniques. Therefore, how does common substrate processing techniques influence the behavior of MHP phenomena such as ion migration and strain? Here, we demonstrate how a hybrid approach of chemical bath deposition (CBD) and nanoparticle SnO2 substrate processing significantly improves the performance of (FAPbI3)0.97(MAPbBr3)0.03 by reducing micro-strain in the SnO2 lattice, allowing distribution of K+ from K-Cl treatment of substrates to passivate defects formed at the interface and produce higher current in light and dark environments. X-ray diffraction reveals differences in lattice strain behavior with respect to SnO2 substrate processing methods. Through use of conductive atomic force microscopy (c-AFM), conductivity is measured spatially with MHP morphology, showing higher generation of current in both light and dark conditions for films with hybrid processing. Additionally, time-of-flight secondary ionization mass spectrometry (ToF-SIMS) observed the distribution of K+ at the perovskite/SnO2 interface, indicating K+ passivation of defects to improve the power conversion efficiency (PCE) and device stability. We show how understanding the role of ion distribution at the SnO2 and perovskite interface can help reduce the creating of defects and promote a more efficient MHP device.

Original languageAmerican English
Pages (from-to)36856-36865
Number of pages10
JournalACS Applied Materials and Interfaces
Volume15
Issue number30
DOIs
StatePublished - 2023

Bibliographical note

Publisher Copyright:
© 2023 American Chemical Society.

NREL Publication Number

  • NREL/JA-5900-87169

Keywords

  • conductive atomic force microscopy
  • metal-halide perovskite
  • time-of-flight secondary ionization mass spectrometry
  • tin oxide

Fingerprint

Dive into the research topics of 'The Role of SnO2 Processing on Ionic Distribution in Double-Cation-Double Halide Perovskites'. Together they form a unique fingerprint.

Cite this