Visible-Light-Induced Water Cleavage and Stabilization of n-Type CdS to Photocorrosion with Surface-Attached Polypyrrole-Catalyst Coating

Arthur J. Frank; Kenji Honda

doi:10.1021/j100208a005

Visible-Light-Induced Water Cleavage and Stabilization of n-Type CdS to Photocorrosion with Surface-Attached Polypyrrole-Catalyst Coating

Arthur J. Frank, Kenji Honda

Chemistry and Nanoscience

National Renewable Energy Laboratory

Research output: Contribution to journal › Article › peer-review

116 Scopus Citations

Abstract

Surface-attached polypyrrole polymer films incorporating a transition-metal catalyst improve markedly the stability of n-type CdS against photocorrosion in aqueous electrolyte while affording the visible-light-assisted water-cleavage reaction. A comparison is made of the oxygen and cadmium production for bare, catalyst-covered, and polypyrrole-catalyst-coated n-type CdS photoanodes.

Original language	American English
Pages (from-to)	1933-1935
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	86
Issue number	11
DOIs	https://doi.org/10.1021/j100208a005 https://doi.org/10.1021/j100208a005
State	Published - 1982

NREL Publication Number

ACNR/JA-233-4339

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title = "Visible-Light-Induced Water Cleavage and Stabilization of n-Type CdS to Photocorrosion with Surface-Attached Polypyrrole-Catalyst Coating",

abstract = "Surface-attached polypyrrole polymer films incorporating a transition-metal catalyst improve markedly the stability of n-type CdS against photocorrosion in aqueous electrolyte while affording the visible-light-assisted water-cleavage reaction. A comparison is made of the oxygen and cadmium production for bare, catalyst-covered, and polypyrrole-catalyst-coated n-type CdS photoanodes.",

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AU - Frank, Arthur J.

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N2 - Surface-attached polypyrrole polymer films incorporating a transition-metal catalyst improve markedly the stability of n-type CdS against photocorrosion in aqueous electrolyte while affording the visible-light-assisted water-cleavage reaction. A comparison is made of the oxygen and cadmium production for bare, catalyst-covered, and polypyrrole-catalyst-coated n-type CdS photoanodes.

AB - Surface-attached polypyrrole polymer films incorporating a transition-metal catalyst improve markedly the stability of n-type CdS against photocorrosion in aqueous electrolyte while affording the visible-light-assisted water-cleavage reaction. A comparison is made of the oxygen and cadmium production for bare, catalyst-covered, and polypyrrole-catalyst-coated n-type CdS photoanodes.

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U2 - 10.1021/j100208a005

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SN - 0022-3654

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SP - 1933

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JO - Journal of Physical Chemistry

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IS - 11

ER -

Visible-Light-Induced Water Cleavage and Stabilization of n-Type CdS to Photocorrosion with Surface-Attached Polypyrrole-Catalyst Coating

Abstract

NREL Publication Number

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