XPS and UPS Studies of Thin Film PV Materials Modified by Reactions in Liquids

Research output: Contribution to conferencePaper

Abstract

Water-based processing steps are ubiquitous in the semiconductor industry, and the field of photovoltaics (PV) is no exception. During chemical bath deposition (CBD) of CdS, complex chemical reactions occurring at surfaces and in solution are poorly understood, yet have been shown to have powerful effects on the performance in terms of reliability and efficiency of finished PV devices. In thepast, electron spectroscopic studies of these reactions have been hampered by the conflicting requirements of ultra-high vacuum and exposure of samples to liquid water. In this paper we present initial results from a new tool at NREL that allows one to conduct atmospheric pressure, liquid phase chemical processes on thin film PV materials and subsequent examination via core and valence levelelectron spectroscopies without exposing samples to air contamination.
Original languageAmerican English
Number of pages5
StatePublished - 2005
Event2004 DOE Solar Energy Technologies Program Review Meeting - Denver, Colorado
Duration: 25 Oct 200428 Oct 2004

Conference

Conference2004 DOE Solar Energy Technologies Program Review Meeting
CityDenver, Colorado
Period25/10/0428/10/04

Bibliographical note

Presented at the 2004 DOE Solar Energy Technologies Program Review Meeting, 25-28 October 2004, Denver, Colorado. Also included in the proceedings available on CD-ROM (DOE/GO-102005-2067; NREL/CD-520-37140)

NREL Publication Number

  • NREL/CP-520-37034

Keywords

  • chemical bath deposition (CBD)
  • devices
  • electron spectroscopic
  • photoelectron spectroscopic (UPS)
  • PV
  • solar cells
  • thin films
  • ultra-high vacuum
  • x-ray photoelectron spectroscopy (XPS)

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